Heat buffer and storage
Scout intake sheet
Challenge description
Within the heat integration cluster of the Institute for Sustainable Process Technology (ISPT), the foundation is laid for a nationally supported cross-sectoral Integrated Circular Heat Program, in which innovation and practice are actively linked. Indeed, for a large number of companies in the agro-food, paper, chemical, horticultural and food sectors, heat is the biggest energy consumer. Therefore, heat technologies need to be vastly integrated to reach a carbon neutral heat supply for all temperature levels by 2050. As this knowledge is spread through various industries and discipline, ISPT wants to present to its partners an overview of the existing technologies that are linked with the (re-)use and storage of heat. This specific scouting case will focus on heat storage and heat buffers. These technologies can have different storage timescales (seasonal or daily). Of interest are the capacity, the efficiency, the flow rate, the temperatures, the size and the TRL. The search should focus on integrated and applied systems (i.e. no lab searches on materials) that either have a low energy output, but many possible applications (as district or domestic heat use) or a high energy output but for a small number of applications (as industrial). However, if the scope is too large, the focus should be set on industrial systems.
Scope
Current known technique(s)
- Sensible heat storage
- Latent heat storage (ex: phase change materials)
- Thermochemical heat storage
Ideal outcome
- Sensible heat storage
- Latent heat storage (ex: phase change materials)
- Thermochemical heat storage
An overview of all the existing methods for storing heat with their specification and suppliers
Minimum viable outcome
A list of all the existing systems to store heat
Objective(s)
- Capacity/Timeframe
- Duration / Timescale
- Size
- Efficiency
- Temperature
Constraint(s)
- Complete system (not a fundamental material in a lab)
- Density
Functions
Action = [store] OR [store] OR [reuse]
Object = [heat] OR [energy] OR [heat]
Environment =
[Residential] OR [Industrial] OR [thermal energy storage] OR [heat] OR [pilot] OR [heat] OR [waste heat] OR [storage] OR [latent] OR [phase change material] OR [water] OR [sensible] OR [solid] OR [PCM] OR [liquid] OR [thermochemical] OR [solid solid] OR [concrete] OR [heat pipe] OR [cavern] OR [sand] OR [heat] OR [storage] OR [oils] OR [thermal] OR [solar cookers] OR [salt] OR [concrete] OR [PCM] OR [high temperature] OR [metal foam] OR [adsorption]
Terminology
- PCM (Phase Change Materials)
Preliminary Results
| Concept | Technology | Selection | |
|---|---|---|---|
|
1. Solid sensible heat storage (S-SHS)
Sensible heat storage systems utilize the heat capacity and the change in temperature of the material during the process of charging or discharging - temperature of the storage material rises when energy is absorbed and drops when energy is withdrawn. These techniques are based on solid materials
|
1.1 Concrete storage pile |
|
0 of 0 |
| 1.2 Granular materials (Sand and rocks) |
|
0 of 0 | |
| 1.3 Natural Rock/cavern storage |
|
0 of 0 | |
| 1.4 Sand |
|
0 of 0 | |
| 1.5 Solid industrial waste byproduct |
|
0 of 0 | |
|
2. Liquid sensible heat storage (L-SHS)
Sensible heat storage systems utilize the heat capacity and the change in temperature of the material during the process of charging or discharging - temperature of the storage material rises when energy is absorbed and drops when energy is withdrawn. These techniques are based on liquids
|
2.1 Aquifer Thermal Energy Storage (ATES) |
|
0 of 0 |
| 2.2 Thermally (Vacuum) insulated water tank |
|
0 of 0 | |
| 2.3 Oils |
|
0 of 0 | |
| 2.4 Molten Salts |
|
0 of 0 | |
| 2.5 Aqueous calcium chloride |
|
0 of 0 | |
| 2.6 Heat and ground pumped hydro energy storage |
|
0 of 0 | |
| 2.7 Ammonium - water storage tanks |
|
0 of 0 | |
|
3. Mix of solid - liquid sensible heat (SL-SHS)
Mix of liquid and solid heat storage
|
3.1 Borehole thermal energy storage (Soil storage) |
|
0 of 0 |
|
4. Solid-solid latent heat storage (SS-LHS)
Solid-solid phase change materials(SS-PCMs) absorb andrelease heat by reversible phase transitions between a (solid) crys-talline or semi-crystalline phase, and another (solid) amorphous,semi-crystalline, or crystalline phase. Different from solid-liquid-PCMs, solid-solid-PCMs retain their bulk solid properties withincertain temperature ranges and are therefore also referred to as ‘‘solid-state” PCMs
|
4.1 Inorganic |
|
0 of 0 |
| 4.2 Organic |
|
0 of 0 | |
| 4.3 Organo-Metallic |
|
0 of 0 | |
| 4.4 Polymeric |
|
0 of 0 | |
|
5. Solid-liquid latent heat storage (SL-LHS)
Generally, LHS systems use the latent heat between solid andliquid phases of the storage medium, whereby the PCM is requiredto be contained or encapsulated within a container to prevent theliquid from leaking; however, the capsules decrease the energydensity of the system and increase the cost of production.
Such storage has potential in heating and cooling buildings, waste heat recovery, offpeak power utilization, heat pump systems, tanks and many other applications
|
5.1 Non-parafins (Organic) |
|
0 of 0 |
| 5.2 Parafin (Organic) |
|
0 of 0 | |
| 5.3 Metallic alloys (Inorganic) |
|
0 of 0 | |
| 5.4 Salt Hydrates and compositions (Inorganic) |
|
0 of 0 | |
| 5.5 Eutetic phase change materials |
|
0 of 0 | |
| 5.6 Alkanes |
|
0 of 0 | |
| 5.7 Fine powdered composite for latent heat storage [R] |
|
0 of 0 | |
| 5.8 Ice/Water Heat pipe for cold storage |
|
0 of 0 | |
| 5.9 Heat Pipes |
|
0 of 0 | |
|
6. Latent Integration technologies
Technolgies to integrate Phase Change Materials into processes.
|
6.1 Building materials filled with PCM |
|
0 of 0 |
| 6.2 Phase Change Material in water tanks |
|
0 of 0 | |
| 6.3 Bed Storage concept |
|
0 of 0 | |
| 6.4 Heat exchanger integration |
|
0 of 0 | |
| 6.5 High temperature concrete as storage media |
|
0 of 0 | |
| 6.6 Micro encapsulated PCM |
|
0 of 0 | |
| 6.7 Nano PCM |
|
0 of 0 | |
| 6.8 Supercooling |
|
0 of 0 | |
| 6.9 Adsorption pump |
|
0 of 0 | |
| 6.10 Steam integration |
|
0 of 0 | |
| 6.11 Heat pipes filled with PCM |
|
0 of 0 | |
| 6.12 Supercritical fluids with PCM |
|
0 of 0 | |
| 6.13 Metal foams |
|
0 of 0 | |
|
7. Thermochemical heat storage (THS)
THS systems can utilise both sorption and chemical reactions to generate heat and in order to achieve efficient and economically acceptable systems, the appropriate reversible reactions (suitable to the user demand needs) need to be identified
|
7.1 Hydroxides (M(OH)2) |
|
0 of 0 |
| 7.2 Metal Carbonates (MCO3) |
|
0 of 0 | |
| 7.3 Metal sulfates (MSO4) |
|
0 of 0 | |
| 7.4 Pure metal oxides (MO) |
|
0 of 0 | |
| 7.5 Zeolite |
|
0 of 0 | |
| 7.6 Silica Gel |
|
0 of 0 | |
| 7.7 Zeo-like Materials |
|
0 of 0 | |
| 7.8 Composite |
|
0 of 0 | |
| 7.9 Metal Hydrides |
|
0 of 0 |
Published 07/28/2019
Based on the case described above we have executed the first line of queries in IGOR^AI. The goal was to obtain a broad set of techniques that store heat. Thermal Energy Storage systems can be classified according to different parameters, being the temperature range of application, the mechanism of energy storage, and the integration within the energy storage concept. As the later can be really broad, it has been chosen to separate the concepts on the mechanism of energy storage and from there on derive later temperature range. Example of storage concepts are shown for PCM materials as both materials and integration process are important. 7 concepts are distinguished based on the results: 1. Solid sensible heat storage (S-SHS) 2. Liquid sensible heat storage (L-SHS) 3. Mix of solid - liquid sensible heat (SL-SHS) 4. Solid-solid latent heat storag (SS-LHS) 5. Solid-liquid latent heat storage (SL-LHS) 6. Latent Integration technologies 7. Thermochemical heat storage (THS) Every concept comprises multiple techniques (49 in total). Below the table, short descriptions, research findings and sources per techniques are listed as well. You can use this information to get a better understanding of the techniques. During the midway meeting, we would like to discuss the techniques and concepts, determine their relevance and select the top selection that needs to be deepened in the second phase of the project.
To determine which technologies are relevant to proceed to the next scouting phase you can play the technology selection game by clicking on the button below.
| Concept | Technology | Selection | |
|---|---|---|---|
|
1. Solid sensible heat storage (S-SHS)
Sensible heat storage systems utilize the heat capacity and the change in temperature of the material during the process of charging or discharging - temperature of the storage material rises when energy is absorbed and drops when energy is withdrawn. These techniques are based on solid materials
|
1.1 Concrete storage pile |
|
0 of 0 |
| 1.2 Granular materials (Sand and rocks) |
|
0 of 0 | |
| 1.3 Natural Rock/cavern storage |
|
0 of 0 | |
| 1.4 Sand |
|
0 of 0 | |
| 1.5 Solid industrial waste byproduct |
|
0 of 0 | |
|
2. Liquid sensible heat storage (L-SHS)
Sensible heat storage systems utilize the heat capacity and the change in temperature of the material during the process of charging or discharging - temperature of the storage material rises when energy is absorbed and drops when energy is withdrawn. These techniques are based on liquids
|
2.1 Aquifer Thermal Energy Storage (ATES) |
|
0 of 0 |
| 2.2 Thermally (Vacuum) insulated water tank |
|
0 of 0 | |
| 2.3 Oils |
|
0 of 0 | |
| 2.4 Molten Salts |
|
0 of 0 | |
| 2.5 Aqueous calcium chloride |
|
0 of 0 | |
| 2.6 Heat and ground pumped hydro energy storage |
|
0 of 0 | |
| 2.7 Ammonium - water storage tanks |
|
0 of 0 | |
|
3. Mix of solid - liquid sensible heat (SL-SHS)
Mix of liquid and solid heat storage
|
3.1 Borehole thermal energy storage (Soil storage) |
|
0 of 0 |
|
4. Solid-solid latent heat storage (SS-LHS)
Solid-solid phase change materials(SS-PCMs) absorb andrelease heat by reversible phase transitions between a (solid) crys-talline or semi-crystalline phase, and another (solid) amorphous,semi-crystalline, or crystalline phase. Different from solid-liquid-PCMs, solid-solid-PCMs retain their bulk solid properties withincertain temperature ranges and are therefore also referred to as ‘‘solid-state” PCMs
|
4.1 Inorganic |
|
0 of 0 |
| 4.2 Organic |
|
0 of 0 | |
| 4.3 Organo-Metallic |
|
0 of 0 | |
| 4.4 Polymeric |
|
0 of 0 | |
|
5. Solid-liquid latent heat storage (SL-LHS)
Generally, LHS systems use the latent heat between solid andliquid phases of the storage medium, whereby the PCM is requiredto be contained or encapsulated within a container to prevent theliquid from leaking; however, the capsules decrease the energydensity of the system and increase the cost of production.
Such storage has potential in heating and cooling buildings, waste heat recovery, offpeak power utilization, heat pump systems, tanks and many other applications
|
5.1 Non-parafins (Organic) |
|
0 of 0 |
| 5.2 Parafin (Organic) |
|
0 of 0 | |
| 5.3 Metallic alloys (Inorganic) |
|
0 of 0 | |
| 5.4 Salt Hydrates and compositions (Inorganic) |
|
0 of 0 | |
| 5.5 Eutetic phase change materials |
|
0 of 0 | |
| 5.6 Alkanes |
|
0 of 0 | |
| 5.7 Fine powdered composite for latent heat storage [R] |
|
0 of 0 | |
| 5.8 Ice/Water Heat pipe for cold storage |
|
0 of 0 | |
| 5.9 Heat Pipes |
|
0 of 0 | |
|
6. Latent Integration technologies
Technolgies to integrate Phase Change Materials into processes.
|
6.1 Building materials filled with PCM |
|
0 of 0 |
| 6.2 Phase Change Material in water tanks |
|
0 of 0 | |
| 6.3 Bed Storage concept |
|
0 of 0 | |
| 6.4 Heat exchanger integration |
|
0 of 0 | |
| 6.5 High temperature concrete as storage media |
|
0 of 0 | |
| 6.6 Micro encapsulated PCM |
|
0 of 0 | |
| 6.7 Nano PCM |
|
0 of 0 | |
| 6.8 Supercooling |
|
0 of 0 | |
| 6.9 Adsorption pump |
|
0 of 0 | |
| 6.10 Steam integration |
|
0 of 0 | |
| 6.11 Heat pipes filled with PCM |
|
0 of 0 | |
| 6.12 Supercritical fluids with PCM |
|
0 of 0 | |
| 6.13 Metal foams |
|
0 of 0 | |
|
7. Thermochemical heat storage (THS)
THS systems can utilise both sorption and chemical reactions to generate heat and in order to achieve efficient and economically acceptable systems, the appropriate reversible reactions (suitable to the user demand needs) need to be identified
|
7.1 Hydroxides (M(OH)2) |
|
0 of 0 |
| 7.2 Metal Carbonates (MCO3) |
|
0 of 0 | |
| 7.3 Metal sulfates (MSO4) |
|
0 of 0 | |
| 7.4 Pure metal oxides (MO) |
|
0 of 0 | |
| 7.5 Zeolite |
|
0 of 0 | |
| 7.6 Silica Gel |
|
0 of 0 | |
| 7.7 Zeo-like Materials |
|
0 of 0 | |
| 7.8 Composite |
|
0 of 0 | |
| 7.9 Metal Hydrides |
|
0 of 0 |
1. Solid sensible heat storage (S-SHS)
BackSensible heat storage systems utilize the heat capacity and the change in temperature of the material during the process of charging or discharging - temperature of the storage material rises when energy is absorbed and drops when energy is withdrawn. These techniques are based on solid materials
1.1 Concrete storage pile
The use of concrete geostructures for energy extraction and storage in the ground is an environmentally friendly and easy way of cooling and heating buildings. With such energy geostructures, it is possible to transfer energy from the ground to buildings by means of fluid-filled pipes cast in concrete. By injecting thermal energy in summer and extracting it in winter, the ground in the area of a building’s piles can be used for seasonal energy storage, as long as the underground water flow in the storage remains low.
Most buildings use piles for the foundation, and these piles can easily contain heat exchangers in contact with the soil. The so-called ‘energy pile’ can thus fulfil a double function: foundation plus heat exchange. Heat pumps can then transfer heat very efficiently from the ground to be building interior and vice-versa. Heat exchange with the ground can be via thermoactive foundations. In thermoactive foundations, foundation piles, also referred to as "thermal piles" or as "energy piles", are used as heat exchangers for supplying low temperature heat to heat pumps. They can also be used for underground storage of warmth supplied by road solar collectors.
Some suppliers also propose heat storage in concrete piles as a flexible installation that is not used as a building foundation and can be used as an add on to an existing building or district (see Energy Nest).
1.2 Granular materials (Sand and rocks)
Granular materials such as sand and rocks are studied to present an additional HTF to represent an efficient and costeffective alternative. Low cost solid particulates can store and transport heat at temperatures over 1000°C.
**_Examples:_**
- Dead Sea salt, concrete bed and Basalt rocks are more economically attractive relative to molten salt plant because they eliminate the extra cost associated with freeze protection, no pressurizing problem, no corrosion. Finally, natural stones can operate at higher temperature and do not suffer from cracking due to cyclic charging and discharging.
- For the purpose of heat recovery, a moving bed heat exchanger (MBHX) is applied and tested. In this study, the dense granular mass is gravitydriven through a heat exchanger. The performance of the MBHX with the utilization of Sand, Basalt, and a Mixture of Sand and Basalt as a granular material was experimentally investigated. It is found that the effectiveness of the MBHX using a mixture of 50% sand and 50% basalt improved by 30% compared to using sand alone.
1.3 Natural Rock/cavern storage
TES system using underground rock carven is considered as an attractive alternative for largescale storage, because of low thermal conductivity and chemical safety of surrounding rock mass. Based on some successful applications of cavern storage and hightemperature storage reported in the literature, the applicabilities and practicabilities of storage media and technologies for largescale cavern thermal energy storage (CTES) were reviewed
Ex: Basalt rocks
1.4 Sand
Seasonal sandbed solar thermal storage systems are an excellent option for storing heat for climates in regions with long periods of freezing temperatures. The present study shows a proof of concept of a sandbed seasonal solar thermal storage that needs additional controls for residential heating application. The system could also be used to provide heat for unoccupied spaces such as garages and greenhouses.
Can also be used for solar powerplants were the intent of the receiver is to be used as a part of a sensible thermal energy storage system for concentrated solar power plants based upon the concept of storing solar heat in sand particles for a later discharge through a specific sandsteam heat exchanger. The results of the analysis indicate low efficiency figures that can be caused by imperfections on the experimental setup and on the original design. Several paths of improvement are discussed in conclusion.
1.5 Solid industrial waste byproduct
Within all the properties that define the suitability of a material to store sensible heat, waste materials stand out especially for their low costs and availability. This heat recovery could be used for cogeneration, energy efficiency measures, passive heat recovery, solar cooling, etc.
In this case, a solid by-product from the potash industry is tested in two different shapes to be used for industrial sensible heat recovery in high temperature, in a range of 100–200 °C. This heat recovery could be used for cogeneration, energy efficiency measures, passive heat recovery, solar cooling, etc. In this case, it is mostly made of NaCl
2. Liquid sensible heat storage (L-SHS)
BackSensible heat storage systems utilize the heat capacity and the change in temperature of the material during the process of charging or discharging - temperature of the storage material rises when energy is absorbed and drops when energy is withdrawn. These techniques are based on liquids
2.1 Aquifer Thermal Energy Storage (ATES)
Aquifer thermal energy storage (ATES) is the storage and recovery of thermal energy in the subsurface. ATES is applied to provide heating and cooling to buildings. Storage and recovery of thermal energy is achieved by extraction and injection of groundwater from aquifers using groundwater wells. Systems commonly operate in a seasonal mode. The groundwater that is extracted in summer, is used for cooling by transferring heat from the building to the groundwater by means of a heat exchanger. Subsequently, the heated groundwater is injected back into the aquifer, which creates a storage of heated groundwater. In wintertime, the flow direction is reversed such that the heated groundwater is extracted and can be used for heating (often in combination with a heat pump). Therefore, operating an ATES system uses the subsurface as a temporal storage to buffer seasonal variations in heating and cooling demand. When replacing traditional fossil fuel dependent heating and cooling systems, ATES can serve as a cost-effective technology to reduce the primary energy consumption of a building and the associated CO2 emissions.
2.2 Thermally (Vacuum) insulated water tank
The solar heat energy is stored in a thermally insulated water tank and used in the heating period. The heat is also stored in the ground if necessary, using the ground loop of the heat pump if the water tank’s temperature rises above a certain threshold. If the temperature is too low for direct heating, then the heat pump can be used to extract the stored energy.
This can also be performed under the form of a large subterranean buffer tank filled with water. Heat and cold can be added to or extracted from the tank through conductivity via its wall.
2.3 Oils
Thermal oils have the advantage that they act both as the heat transfer and the heat storage medium for medium to high temperature domestic applications. These applications include steam generation and cooking of food. Although thermal oils are more expensive than water which is in abundance, the use of water in medium to high temperatures is limited by its boiling point. For small scale domestic applications which require non-sophisticated heat exchangers, thermal oils can be utilized.
2.4 Molten Salts
Molten salts can be employed as a thermal energy storage method to retain thermal energy. Presently, this is a commercially used technology to store the heat collected by concentrated solar power (e.g., from a solar tower or solar trough). The heat can later be converted into superheated steam to power conventional steam turbines and generate electricity in bad weather or at night. The salt melts at 131 °C (268 °F). It is kept liquid at 288 °C (550 °F) in an insulated "cold" storage tank. The liquid salt is pumped through panels in a solar collector where the focused sun heats it to 566 °C (1,051 °F). It is then sent to a hot storage tank. With proper insulation of the tank the thermal energy can be usefully stored for up to a week.[15] When electricity is needed, the hot molten-salt is pumped to a conventional steam-generator to produce superheated steam for driving a conventional turbine/generator set as used in any coal or oil or nuclear power plant
Different existing concept and salts: Two tanks / One tank storage using NaNo3/ KNO3 / Ca(NO3)2
2.5 Aqueous calcium chloride
A new concept for longterm solar storage is based on the absorption properties of aqueous calcium chloride. Water, diluted and concentrated calcium chloride solutions are stored in a single tank. An immersed heat exchanger and stratification manifold are used to preserve longterm sorption storage, and to achieve thermal stratification. The feasibility of the concept is demonstrated via measurements of velocity, CaCl2 mass fraction, and temperature in a 1500 liter prototype tank during sensible charging.
2.6 Heat and ground pumped hydro energy storage
Using compressed water system to store heat.
A startup and a research project have been found on this topic. No direct suppliers
- GLIDES: A novel Ground Level Integrated Diverse Energy Storage (GLIDES) system which can store energy via input of electricity or heat and deliver dispatchable electricity. The proposed system is lowcost and hybridizes compressed air and pumpedstorage approaches that will allow for the offpeak storage of intermittent renewable energy for use during peak times. GLIDES, stores electricity mechanically in the form of compressed gas that displaces water in high-pressure vessels.
- Insentropic: PHES Thermal Stores are split into layers to achieve high efficiency of thermal transfer, low pressure drop and higher energy density than other 'packed bed' stores. The PHES Thermal Stores work by direct heat exchange between high pressure gas and particles of crushed rock or gravel. It will be a stand-alone energy storage system called Pumped Heat Energy Storage (PHES). The cycle uses a proprietary reciprocating heat pump/engine (developed in-house). It will take electricity from the grid to charge the system.
2.7 Ammonium - water storage tanks
The electricity is first transformed into the chemical potential of the working fluid by means of varying the refrigerant or absorbent mass fraction in the working fluid storage tank. When cooling, heating or dehumidifying is needed, the potential stored in the tank can then be transformed into cold/heat energy by means of absorption refrigeration/heat pump or into dehumidification/desiccation energy by means of absorption dehumidification.
3. Mix of solid - liquid sensible heat (SL-SHS)
BackMix of liquid and solid heat storage
3.1 Borehole thermal energy storage (Soil storage)
Borehole thermal energy storage (BTES) system is an underground structure for storing large quantities of solar heat collected in summer for use later in winter. It is basically a large, underground heat exchanger. To Store solar energy in the soil under and near the building. In unsaturated soil or in rock the most interesting techniques are heat exchangers in vertical boreholes. Via these heat exchangers the energy is transferred to the ground which serves as heat capacity and is heated up to the required temperatures. Depending on the temperature level, the thermal energy is, extracted either by a heat pump (low temperature ground storage, 0°C-40°C) or directly (high temperature ground storage, 40°C-80°C) and delivered to the consumers. As a result of the limited thermal conductivity the heat losses are rather moderate and storage efficiencies of 70% can be reached. In contrast good thermal contact between the heat exchangers and the ground is required to allow a good heat transfer rate per unit area of the heat exchanger tube. In unconsolidated soils like clay, silt, or sand, heat capacity and thermal conductivity are strongly dependent on the water content especially at higher temperatures (> 60°C) . In this region water losses can occur because of vapour diffusion along the temperature gradient which can lead to dry-out and cracking in the area surrounding the heat exchanger tubes in the worst
The capital cost of a large Borehole thermal energy storage system can be significant, as a large number of geothermal boreholes will need to be drilled, compared to just a few thermal wells for an ATES system. However, the installation cost should be similar to conventional GSHP systems, and the higher COP values will result in a lower total life-cycle cost than a conventional GSHP system. Both closed-loop geothermal systems will have a lower life-cycle cost than a conventional fossil-fuel fired HVAC system. Because BTES is a closed-loop geothermal technology, there should be little difficulty in obtaining permits. Typically, the most common constraint is on the available land area in which to construct the GHX array.